SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 1 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) Section 1. Identification of the substance or the mixture and of the supplier 1.1 Product Identifier Product identifier: Rose Absolute Moroccan; CAS: 84604-12-6 Other identifiers: Rose, Rosa centifolia, ext. 1.2 Relevant identified uses of the substance of mixture and uses advised against Product uses: Flavours,Fragrances 1.3 Details of the supplier of the safety data sheet Company name: J C Buck Ltd Unit B1, Hubert Road Brentwood Essex CM14 4JY England Company address: Contact: Matthew Buck E-Mail address: regulatory@jcbuck.co.uk Company phone: +44 (0) 1708 437099 1.4 Emergency telephone number Emergency phone: +44 (0) 1708 437099 2.1 Classification of the substance or mixture Section 2. Hazards identification Classification under Regulation (EC) No 1272/2008 Class and category of danger: Acute Toxicity - Oral Category 4 Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 1 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H302, Harmful if swallowed. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H412, Harmful to aquatic life with long lasting effects. J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 2 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger H302, Harmful if swallowed. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H412, Harmful to aquatic life with long lasting effects. Hazard statements: M factor: None Supplemental None Information: P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P270, Do not eat, drink or smoke when using this product. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/312, IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P330, Rinse mouth. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Precautionary statements: Pictograms: Other hazards: None 2.3 Other hazards J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 3 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) 3.1 Substances Product identifier: Rose Absolute Moroccan; CAS: 84604-12-6 Section 3. Composition / information on ingredients Name EC REACH Registration No. CAS Contains: Max Classification for (CLP) 1272/2008 Phenethyl alcohol 60-12-8 200-456-2 85.00% Acute Tox. 4-Eye Irrit. 2;H302-H319,- dl-Citronellol 106-22-9 203-375-0 14.00% Skin Irrit. 2-Eye Irrit. 2- Skin Sens. 1B;H315- H317-H319,- Geraniol 106-24-1 203-377-1 6.50% Skin Irrit. 2-Eye Dam. 1-Skin Sens. 1;H315- H317-H318,- Eugenol 97-53-0 202-589-1 1.50% Eye Irrit. 2-Skin Sens. 1B;H317-H319,- Benzyl alcohol 100-51-6 202-859-9 1.50% Acute Tox. 4-Eye Irrit. 2;H302-H319,- d,l-Limonene (isomer unspecified) 7705-14-8 231-732-0 1.00% Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- Aquatic Chronic 1; H226-H304-H315- H317-H410,- Eugenyl methyl ether 93-15-2 202-223-0 0.40% Acute Tox. 4-Muta. 2- Carc. 2;H302-H341- H351,- alpha-Pinene 80-56-8 201-291-9 0.20% Flam. Liq. 3-Acute Tox. 4-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1- Aquatic Acute 1- Aquatic Chronic 1; H226-H302-H304- H315-H317-H410,- 4.1 Description of first aid measures Section 4. First-aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. 4.2 Most important symptoms and effects, both acute and delayed Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. 4.3 Indication of any immediate medical attention and special treatment needed J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 4 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) None expected, see Section 4.1 for further information. 5.1 Extinguishing media SECTION 5: Firefighting measures Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. Section 6. Accidental release measures 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. 7.1 Precautions for safe handling: Section 7. Handling and storage Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Flavours,Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 5 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. 9.1 Information on basic physical and chemical properties Appearance: Dark red to orange brown liquid Section 9. Physical and chemical properties Odour: Sweet floral rosy Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 87 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: Not determined Vapour density: Not determined Relative density: 0.9000 - 1.1000 Solubility(ies): Soluble in ethanol. Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 6 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) 9.2 Other information: None available 10.1 Reactivity: Section 10. Stability and reactivity Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. 11.1 Information on toxicological effects Section 11. Toxicological information Acute Toxicity: Acute Toxicity - Oral Category 4 Acute Toxicity Oral 1662 Acute Toxicity Dermal 2507 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Skin Corrosion / Irritation Category 2 Serious eye damage/irritation: Eye Damage / Irritation Category 1 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture LC50 Route Benzyl alcohol 100-51-6 202-859-9 2500 Not available 1620 Not available Phenethyl alcohol 60-12-8 200-456-2 2500 Not available 1610 Not available Component CAS LD50/ATE Oral LD50/ATE Dermal LC50/ATE Inhalation EC J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 7 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) Refer to Sections 2 and 3 for additional information. 12.1 Toxicity: Section 12. Ecological information Harmful to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects: Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14.1 UN number: Not classified Section 14. Transport information 14.2 UN Proper Shipping Name: - 14.3 Transport hazard class(es): Not classified Sub Risk: Not classified 14.4. Packing Group: Not classified 14.5 Environmental hazards: Not environmentally hazardous for transport 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not classified 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Section 15. Regulatory information None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other information Concentration % Limits: EDI 2A=5.99% EH C3=20.83% SCI 2=46.51% EDI 1=46.15% EDI 2=5. 99% SS 1=7.14% Total Fractional Values: EDI 2A=16.70 EH C3=4.80 SCI 2=2.15 EDI 1=2.17 EDI 2=16.70 SS 1=14. 00 J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 8 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) Key to revisions: SECTION 3: Composition/information on ingredients Key to abbreviations: Abbreviation Meaning Acute Tox. 4 Acute Toxicity - Oral Category 4 Aquatic Acute 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Aquatic Chronic 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 Asp. Tox 1 Aspiration Hazard Category 1 Carc. 2 Carcinogenicity Category 2 Eye Dam. 1 Eye Damage / Irritation Category 1 Eye Irrit. 2 Eye Damage / Irritation Category 2 Flam. Liq. 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects (exposure route). H351 Suspected of causing cancer (exposure route). H410 Very toxic to aquatic life with long lasting effects. Muta. 2 Germ Cell Mutagenicity Category 2 P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating and lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing vapour or dust. P264 Wash hands and other contacted skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection/face protection. P281 Use personal protective equipment as required. P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301/312 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352 IF ON SKIN: Wash with plenty of soap and water. J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom. SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: Rose Absolute (Centifolia) CAB0001 Version: 7 9 ( 9 ) Issue date: 03/11/2021 Page Version: 7 (07/04/2021) P303/361/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P330 Rinse mouth. P331 Do not induce vomiting. P333/313 If skin irritation or rash occurs: Get medical advice/attention. P337/313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391 Collect spillage. P403/235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container to approved disposal site, in accordance with local regulations. Skin Irrit. 2 Skin Corrosion / Irritation Category 2 Skin Sens. 1 Sensitization - Skin Category 1 Skin Sens. 1B Sensitization - Skin Category 1B The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee. J C Buck Ltd, Unit B1 Hubert Road, Brentwood, Essex, CM14 4JY, United Kingdom.